| 四—(3—甲氧基—4—羟基苯基)卟啉化合物及其钴配合物的合成、鉴定和催化氧化活性 |
| SYNTHESIS AND CATALYTIC PROPERTIES OF TETRAKIS(3-METHOXY-4-HYDROXYPHENYL)PORPHYRIN COMPLEX |
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| 摘要: 合成了四—(3—甲氧基—4—羟基苯基)卟啉及其金属钴配合物,并用元素分析,H NMR UV、IR及DSC谱进行了结构表征,通过在所合成的钴卟啉配合物存在时氢醌的氧化反应和硫醇化反应,表明它具有催化活性。 |
| 关键词: 钴 卟啉 氯醌 正丁硫醇 催化 |
| 基金项目: |
| Abstract: The synthesis and characterization for a new porphyrin-tetrakis(3-mcthoxy-4-hydroxy-phcnyl)porphyrin and its cobalt complex have been report. The structure and property of this complex were studied by elemental analysis, infrared, 1H NMR,UV and DSC spectroscopy. The catalve oxidations of quinhydrone and n-butyl mcrcaptan by the cobalt porphyrin were |
| Keywords: cobalt purphyrin catalysis quishydrone n-butyl mercaptan |
| 投稿时间：1988-05-12 |
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| 侯秀峰,吴祺.四—(3—甲氧基—4—羟基苯基)卟啉化合物及其钴配合物的合成、鉴定和催化氧化活性[J].无机化学学报,1990,6(4):439-442. |
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