希土高氯酸盐与N,N'—二(2—吡啶亚甲基)—1,2—乙二胺配合物的合成及性质研究
PREPARATION AND CHARACTERI ZATION OF THE COMPLEXES OF RARE EARTH PERCHLORATES WITH N,N'-BIS(2-PYRIDYLMETHYLENE)-1,2-ETHANEDIAMINE
作者单位
王长青  
谭民裕  
甘新民  
唐宁  
摘要: 自六十年代以来,希土离子与芳香胺及其衍生物的配合物研究受到人们的普遍重视。
关键词: N,N′-二(2-吡啶亚甲基)-1,2-乙二胺  希土高氯酸盐  配合物
基金项目: 国家自然科学基金
Abstract: The solid complexes of rare earth perehlorates with N,N'-bis(2-pyridylmethylenc)-1,2-ethanediamine (bpme) having the formula of Ln(Cu14H14N4)2(ClO4)3·nH2O (Ln-La-Nd, Sm-Er,Y; n=1,2) have been prepared in methanol. Their composition and properties have been studied by elemental analysis, IR and UV spectra, TG-DSC and molar conductance.
Keywords: N,N'-bis(2-pyrldylmethylene)-1,2-ethanediamine  rare earth perchlorate  complex
投稿时间:1988-10-10 
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王长青,谭民裕,甘新民,唐宁.希土高氯酸盐与N,N'—二(2—吡啶亚甲基)—1,2—乙二胺配合物的合成及性质研究[J].无机化学学报,1990,6(4):474-476.
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