| 1-苯基-3-甲基-4-苯甲酰基-5-吡唑酮与甲基膦酸二(1-甲基庚基)酯对Pb(Ⅱ)、Cd(Ⅱ)和Cu(Ⅱ)的萃取机理研究 |
| EXTRACTION MECHANISM OF Pb(Ⅱ), Cd(Ⅱ)AND Cu(Ⅱ)WITH 1-PHENYL-3-METIIYL-4-BENZOYL-PYRAZOL-5-QNE(PMBP)AND DI(1-METHYLHEPTYL)METKYLPHOSPHONATK(P350) |
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| 摘要: 本文用两相滴定法研究了1-苯基-3-甲基-4-苯甲酰基-5-吡唑酮(PMBP,简写为HA)与甲基膦酸二(1-甲基庚基)脂(P350,简写为B)对Pb2+、Cd2+和Cu2+离子在不同的有机溶剂中的萃取机理.确定了萃合物的组成分别为:MA2(M=Pb2+、Ca2+、Cu2+);MA2·HA(M=Cd2+);MA2·B(M=Pb2+、Cd2+)和MA2·2B(M=Cd2+),同时求得了相应的萃合常数β值. |
| 关键词: 萃取 协同萃取 机理 铅离子 镉离子 铜离子 |
| 基金项目: |
| Abstract: The chclatc extraction of Pb(Ⅱ), Cd(Ⅱ)and Cu(Ⅱ)with PMBP(HA)in benzene and syncrgistlc extraction of Pb(Ⅱ)and Cu(Ⅱ)with PMBP and P350(B)in each of eight organic solvents were investigated by using the two-phase titration method. The formulas of the extracted species have been suggested and the extracting equilibrium constants B2im corresponding to the extracted chclatcs MA2(HA)i mB have been evaluated(abbreviated). |
| Keywords: extraction synergisitc extraction mechanism lead lon esdism lon copper lon |
| 投稿时间：1988-10-21 |
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| 吴斌,王开毅,张祥麟.1-苯基-3-甲基-4-苯甲酰基-5-吡唑酮与甲基膦酸二(1-甲基庚基)酯对Pb(Ⅱ)、Cd(Ⅱ)和Cu(Ⅱ)的萃取机理研究[J].无机化学学报,1991,7(3):262-266. |
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