| 固相配位化学反应研究——ⅩⅩⅩⅡ.镍钨硫簇合物的固相合成 |
| STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅫ SOLID STATE PREPARATIONS OF FOLYNUCLEAR Ni-W-S COOPPINATIQN COMPOUNDS |
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| 摘要: 本文首次成功地在低热温度下固相反应合成镍钨硫杂核金属簇合物:[(n-Bu)4N]2[Ni(WS4)2]和[(n-Bu)4N]2[Ni(WOS4)2].用EXAFS、IR、UV.元素分析、TG-DTA等手段对上述化合物进行了表征.研究了温度、气氛等条件对合成反应的影响. |
| 关键词: 硫代钨酸铵 钨镍原子簇合物 固相反应 |
| 基金项目: 联合国科教文组织资助;国家自然科学基金委员会资助;国家教委博士点基金会资助 |
| Abstract: The solid stale reactions have been successfully used in tlic preparations of titled clusters at first. The following clusters have been synthizcd: [(n-Bu)4N)2 [ Ni(WS4)2] and C(n-Bu)4N)2 [Ni(WOS4)2] . Their structures have been rigorously characterized by extended X-ray absorption fine structure(EXAFS), vibrational spcctroscopy and other physical methods. The influences of temperature, gas, etc. on solid slate reactions and TG-DTA curve of the cluster [(n-Bu)4N]2[Ni(WS4)2] have been discussed. |
| Keywords: thlotunstate tungsten cluster solld state reactlon |
| 投稿时间：1989-01-26 |
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| 高逢君,朱慧珍,忻新泉,戴安邦,吉文斌,马礼敦.固相配位化学反应研究——ⅩⅩⅩⅡ.镍钨硫簇合物的固相合成[J].无机化学学报,1991,7(3):318-322. |
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