| 冠醚配合物的研究——Ⅻ.电导法研究若干甲基冠醚与Na+、K+在DMF中的配位反应 |
| STUDIES ON CROWN COMPOUNDS XⅡ.COORDINATION REACTION OF METHYL-CROWNS WITH Na+ AND K+ IN DMF BY CONDUCTOMETRIC TITRATION |
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| 摘要: 本文采用微量电导滴定技术和计算机拟合,获得在DMF中Na+和K+与2,3-苯并-11-甲基-18-冠-6(BCl-18C6),2,3-苯并-8,15-二甲基-18-冠-6(BC2-18C6),2,3-苯并-8,11,15-三甲基-18-冠-6(BC3-18C6)的配合物的稳定常数及反应热焓,并对所得结果进行了讨论。 |
| 关键词: 甲基冠醚 碱金属离子 稳定常数 热焓 |
| 基金项目: |
| Abstract: The stability constants of coordination compounds and enthalpies of coordination re-action of 2,3-bcnzo-11-methyl-18-crown-6(BCl-18C6),2,3-benzo-8,11,15-dimethyl-18-crown-6(BC2-18C6) and2,3-benzo-8,11,15-trimethyl-18-crown-6(BC3-18C6) with Na+ and K+ in DMF were determined by microconductometric titration and computer fitting. The results obtained were discussed. |
| Keywords: methylcrown alkaline metal ion stability constant enthalpy |
| 投稿时间：1990-10-15 |
| 摘要点击次数: 1118 |
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| 王志林,陆国元,罗勤慧.冠醚配合物的研究——Ⅻ.电导法研究若干甲基冠醚与Na+、K+在DMF中的配位反应[J].无机化学学报,1992,8(3):246-249. |
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