测接触角法确定偶联剂的最佳用量
DETERMINATION OF THE OPTIMUM AMOUNT OF COUPLING AGENT WITH CONTACT ANGLE METHOD
作者单位
沈健 南京大学化学系, 南京 210008 
嵇根定 南京大学化学系, 南京 210008 
黄艳 南京大学化学系, 南京 210008 
黄元富 南京大学化学系, 南京 210008 
摘要: 偶联剂是一类能在无机填料和聚合物基材之间形成“分子桥”、改善两者之间相容性或提高两者之间相互作用能力的化合物。将经偶联剂改性的无机填料填充到聚合物中可以制得成本低、性能好的复合材料[1,2]。由于偶联剂用量多少将对复合材料的性能产生较大影响[3],因此建立一种准确、简便地确定偶联剂最佳用量的方法有着十分重要的理论和实际应用意义。
关键词: 测接触角法  偶联剂的最佳用量  表面能及其分量  填充聚烯烃  硅灰石
基金项目: 
Abstract: In this paper the influence of the amount of coupling agent (NDS-01) on the disperse part of the surface energy Xsd(Xsd=rsd/ (rsd+sp) is studied by determination of contact angle. It is found that rsd increases firstly and then decreases a little after reaching its maximum point with the increase of NDS-01 amount. Comparing with mechanical properties of filled polyolefine, we concluded that the amount of coupling agent which results in the maximum of rsd may be taken as the optimum one. The results of determination of contact angle are more exact than those of other methods.
Keywords: contact angle method  optimum amount of coupling agent  surface energy and its component  filled polyolefine  wollastonite
投稿时间:1991-12-28 
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沈健,嵇根定,黄艳,黄元富.测接触角法确定偶联剂的最佳用量[J].无机化学学报,1992,8(3):321-322.
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