| 铜(Ⅱ)与N(2-羟基乙基)水杨醛亚胺配合物的合成、结构和热分解 | |
| SYNTHESIS, STRUCTURE AND THERMAL DECOMPOSITION OF THE COMPLEX OF Cu(Ⅱ) WITH N(2-HYDROXYETHYL) SALICYLALDIMINO | |
| 摘要: 人们在探索新的有效抗癌药物时,发现了一些Schiff碱及其和某些金属生成的配合物具有抗癌作用[1,2]。为研究此类配合物的抗癌作用和结构的关系,我们合成了一系列Schiff碱类配合物[3,4]。 | |
| 关键词: 铜 配合物 结构 热分解 | |
| 基金项目: | |
| Abstract: The complex of Cu(Ⅱ) with N(2-hydroxyethyl) salicyldimino Cu(OC6H4CHNCH2-CH2OH)2 was perpared. Its structure was determined by means of four-cycle diffractometer. It was found that the crystal belongs to the monoclinic system with group P21, and the unit ceil parameters are: a=18.302Å, b= 4.806Å, c= 19.781Å, β=98.87°, V= 1718Å3, Z=4, Mr=391.9, Dc= 1.52g/cm3, F(000) = 820. The structure was solved by direct method and the final R= 0.076. The process of its thermal decomposition was investigated by means of DTA and TG techniques. | |
| Keywords: copper complex structure thermal decomposition | |
| 投稿时间：1990-10-04 | |
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| 崔学桂,刘德信,李晓燕,孙宏建,李凤玲,许义斌,林秀云,林政炯.铜(Ⅱ)与N(2-羟基乙基)水杨醛亚胺配合物的合成、结构和热分解[J].无机化学学报,1992,8(3):329-332. | |
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