| 大环配体过渡金属配合物——Ⅵ.四(对-二硫杂环己烯)四氮杂卟啉钒(Ⅳ)、锰(Ⅱ)和钼(Ⅴ)配合物的合成与表征 |
| TRANSTION METAL COORDINATION COMPOUNDS OF MACROCYCLIC LIGAND VI. SYNTHESES AND CHARACTERIZATION OF TETRA (1,4-DITHIACYCLOHEXENE)TETRAAZAPORPHYRIN COORDINATION COMPOUNDS WITH V(IV), Mn(Ⅱ), AND Mo(V) IONS |
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| 摘要: d过渡金属含硫四氮杂卟啉配合物,是一类新型功能性配合物,因其具有比金属卟啉、金属酞菁更为优异的光电和催化特性,故近十多年来颇受重视[1-3]。我们对该类金属配合物及其自由配体的合成、性质和某些功能,正在进行广泛和深入的研究。本文简要报道标题配合物的合成、元素分析,红外光谱、电子光谱和电子顺磁共振谱的表征。 |
| 关键词: 含硫四氮杂卟啉 配合物 红外光谱 电子光谱 顺磁共振波谱 钒 锰 钼 |
| 基金项目: 国家自然科学基金 |
| Abstract: In the basic of rcfcrrencc[6]> and [7], the title compounds VCl2TTTAP, MnTTTAP, and MoO(OH)TTTAP have been synthesized according to the solid reaction method from prepared 2,3-dicyano-1,4-dithiacyclohcxcnc and metal acetate. Study has been made of the infrared and electronic spectra for the transition metal coordination compounds of this ligand in combination with rcfcrrencc[6]. The TTTAP system is similar to PC and TAP (tctraazapor-phyrin) et al. systems in infrared and electronic spectra. |
| Keywords: thio-tetraazaporphyrin coordination compound synthesis IR spectrum UV spectrum EPR spectra vanadium manganese molybdenum |
| 投稿时间：1990-12-06 |
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| 吴革非,陈晓贵,姚生蓬,彭正合,秦子斌.大环配体过渡金属配合物——Ⅵ.四(对-二硫杂环己烯)四氮杂卟啉钒(Ⅳ)、锰(Ⅱ)和钼(Ⅴ)配合物的合成与表征[J].无机化学学报,1992,8(3):336-338. |
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