高分子-AlCuCl4膜及其气体透过行为探讨
AN INVESTIGATION IN CHARACTERIZATION AND GAS PERMSELECTIVITIES OF POLYMER-AlCuCl4 MEMBRANE
作者单位
施孝遹 中国科学院兰州化学物理研究所, 兰州 730000 
潘光明 中国科学院兰州化学物理研究所, 兰州 730000 
孙社营 中国科学院兰州化学物理研究所, 兰州 730000 
摘要: 把对一氧化碳具有选择吸附功能的液体吸附剂(AlCuCl4-甲苯溶液和AlCuCl4-Pst-甲苯溶液)引入到高分子(EC、Pst、ABS、CA)膜材料中,制成固体膜,考察了膜的气体透过性能,同时初步得出结果认为,膜中的AlCuCl4以电荷转移配合物形式与高分子配位结合.
关键词:   气体透过性能  电荷转移  配合物  配位结合
基金项目: 
Abstract: The liquid adsorbents possessing selective adsorbing function for carbon monoxide (AlCuCl4-tolueue solution and AlCuCl4-Pst-toluene solution) was incorporated into polymer membrane materials (EC, Pst, ABS, CA), then the gas separation membranes were made, and characterization their gas permselectivities were studied. The results showed that, the AlCuCl4 in membrane is linked with functional group of polymers as a charge-transfer complexes.
Keywords: membrane  gas permeability  charge-transfer complex  coordination
投稿时间:1991-08-20 
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施孝遹,潘光明,孙社营.高分子-AlCuCl4膜及其气体透过行为探讨[J].无机化学学报,1993,9(1):59-64.
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