| 鸟嘌呤与Cu(Ⅰ)配位作用的极谱研究 |
| STUDY ON THE COORDINATION OF GUANINE WITH Cu(I) BY MEANS OF D. C. POLAROGRAPHY |
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| 摘要: 在0.02mol/L NaHCO3-0.05mol/L Na2SO4(pH9)介质中,对鸟嘌呤与Cu(Ⅰ)的配位作用进行了极谱研究,测定了鸟嘌呤与Cu(Ⅰ)配位的配体数(2)和该配合物的条件形成常数(β1=1.80×1014,β2=2.85×1018),并对DcFord-Hume公式的适用性作了讨论. |
| 关键词: 配合物条件形成常数 鸟嘌呤Cu(Ⅰ)配合物 鸟嘌呤 极谱法 |
| 基金项目: 国家自然科学基金 |
| Abstract: By means of D.C. polarography, the coordination of guaninc with Cu(I) was studied in the system of 0.02mol/L NaHCO3-0.05mol/L Na2SO4(pH9). The complexes are irreversibly reduced at the dropping mercury electrode. DcFord-Hume's method was used for the determination of the coordination number and the conditional formation constants of Cu(I)-guanine complexes. The results are 1.80×l014(CuG) and 2.85×l018(CuG2), respectively, and the adapt of DcFord-Hume's equation was discussed briefly. |
| Keywords: conditional formation constant of complex copper(Ⅰ) complex guanine polarography |
| 投稿时间：1991-12-20 |
| 摘要点击次数: 1122 |
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| 孙贤祥,陈洪渊.鸟嘌呤与Cu(Ⅰ)配位作用的极谱研究[J].无机化学学报,1993,9(1):103-106. |
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