| 间位取代四苯基卟啉铁(Ⅲ)的紫外可见光谱及其与二乙胺轴配反应的研究 |
| STUDY ON AXIAL COORDINATION OF META-SUBSTITUTED (TETRAPHENYL-PORPHINATO) IRON(Ⅲ) CHLORIDE AND THEIR UV-VIS SPECTRA |
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| 摘要: 研究了二氯甲烷溶液中二乙胺(L)与氯合(meso-四-间甲基苯基卟啉)铁(Ⅲ)的轴向配位反应.用光谱法测得不同温度下反应的平衡常数,求得(m-CH3)TPPFe(Ⅲ)Cl+L=(m-CH3)TPPFe(Ⅲ)Cl·L反应的标准摩尔焓和摩尔熵.同时,对反应的动力学与反应机理进行了研究.也研究了反应物和产物的紫外可见光谱,并讨论了取代基及轴向配体对铁卟啉紫外可见光谱的影响。 |
| 关键词: 氯合间位取代四苯基卟啉铁(Ⅲ) 平衡常数 紫外可见光谱 动力学 |
| 基金项目: 国家自然科学基金资助课题 |
| Abstract: The axial coordination reaction of tctra(mcta-mcthylphcnyl) porphinatoiron(Ⅲ) chloride with dicthylaminc(L) in dichloromcthanc was reported in this paper.The equilibrium constants were measured by spectral technique and the standard change of molar enthalpy(ΔrHmø) and molar entropy(ΔrSmø) of the reaction were calculated.On the other hand,the kinetics of the reaction was also studied and the mechanism was supposed as follows:Fe(Ⅲ)P+L Fe(Ⅲ)PL Last,the UV-Vis spectra of meta-substitute tetraphenylporphinato iron(Ⅲ) chloride were measured by means of Bekman Du 8B Spcctrophotomctcr and the effects of the substitucnts in the porphyrin and axial ligand to the spectra were discussed. |
| Keywords: tetraphenylporphinato iron(Ⅲ)chloride equilibrium constant UV-Vis spectra kinetics |
| 投稿时间：1991-11-15 |
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| 朱志昂,黄小群,江冬青,于鸿毅,陈荣悌.间位取代四苯基卟啉铁(Ⅲ)的紫外可见光谱及其与二乙胺轴配反应的研究[J].无机化学学报,1993,9(2):139-144. |
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