| 酞菁铑的合成及其性质研究 |
| SYNTHESIS, ELECTROCHEMISTRY AND SPECTROELECTROCHEMISTRY OF RHODIUM(Ⅱ) PHTHALOCYANINE COMPLEX |
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| 摘要: 本文合成了铑(Ⅲ)酞菁配合物,用循环伏安法研究了该配合物在二甲基甲酰胺、吡啶和二甲亚砜等有机溶剂中的电化学,并利用薄层透光电极电解;获得了该配合物四种不同氧化态时的电子光谱,并对电极反应机理及其产物进行了讨论. |
| 关键词: 铑 酞菁 合成 电化学 光谱电化学 |
| 基金项目: |
| Abstract: Rhodium(Ⅲ) phthalocyanine was prepared.It's electrochemistry was studied in dimethylmamide,pyridine and dimethylsulfoxide.The redox mechanisms and species on the electrode were discussed.With the use of an optically thin electrode,the electronic absorption spectra of 4 different oxidation states were also reported. |
| Keywords: rhodium phthalocyanine synthesis electrochemistry spectroelectrochemistry |
| 投稿时间：1991-11-30 |
| 摘要点击次数: 1192 |
| 全文下载次数: 1237 |
| 刘巍.酞菁铑的合成及其性质研究[J].无机化学学报,1993,9(2):166-171. |
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