| 高硅Y型沸石的研制及性能——Ⅰ.LiNaY沸石的SiCl4脱铝 |
| HIGH-SILICA Y ZEOLITE SYNTHESIS AND ITS PROPERTIES I. DEALUMINATION OF LiNaY WITH SiCl4 |
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| 摘要: LiNaY沸石经SiCl4气相脱铝补硅而制得一系列高硅铝比Y沸石,用XRD,IR测定脱铝沸石的晶胞参数α0,骨架硅铝比SiF/AlF,和其结构稳定性.用TG—DTA法研究其表面憎水性能.用真空重量法研究其吸附性能。结果表明随着骨架脱铝量的增加其结构稳定性和憎水性都随之增加.对极性分了的吸附能力随之下降。 |
| 关键词: Y沸石 脱铝 表征 |
| 基金项目: |
| Abstract: Highly crystalline zeolites with Si/Al ratio range from 3 to 100 have been prepared by dcalumination of LiNaY with SiCl4.Unit cell parameter a0 and framework composition Si/Al have been measured by X-ray diffraction analysis and infrared spectra of their framework.Property of hydrophobicity on a scries of samples of zeolite LiNaY dcaluminated have been performed by thcrmogravimctric analysis.Adsorption isotherms for water,benzene and hexanc on a scries of samples of dcaluminated LiNaY zeolite have been discussed. |
| Keywords: zeolite dcalumination characterization |
| 投稿时间：1992-01-10 |
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| 孙德坤,鲍书林,陈晶.高硅Y型沸石的研制及性能——Ⅰ.LiNaY沸石的SiCl4脱铝[J].无机化学学报,1993,9(2):194-198. |
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