| [Fe(Phen)3](ClO4)3与Na2SO3在室温下的固相氧化还原反应 |
| SOLID STATE REDOX REACTION OF [Fe(phen)3](ClO4)3·H2O WITH SODIUM SULFITE AT ROOM TEMPERATURE |
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| 摘要: 本文研究室温下[Fe(phen)3](ClO4)3·H2O与Na2SO3发生的固-团相氧化还原反应.用Mossbauer谱、XRD、IR、元素分析和磁化率测定等手段表征了反应24h后的团相产物.实验表明,室温下该反应速度快,反应进行完全. |
| 关键词: Mossbauer谱 室温固相反应 铁配合物 氧化还原反应 |
| 基金项目: 国家自然科学基金;国家教委博士点基金;湖北省教委科研基金 |
| Abstract: This note reports the solid state redox reaction of [Fe(phen)3](ClO4)3·H2O with sodium sulfite at room temperature. It has been found out that the reaction is complete, and the reaction velocity is fast. Mossbauer spectrometry, clemental analysis, XRD, FTIR and Magnetic susceptibility were used to characterize the solid state product.The Mossbauer spectra shows that the valence of iron has changed during the reaction.lron existed in low-spin fe(Ⅲ)complex before reaction. While iron existed in low-spin Fo(Ⅱ)complex after reaction. They are all octahedral symmetrical six-coordinated complexes. |
| Keywords: Mossbauer spectrometry redox reaction iron complex solid state reaction at room temperature |
| 投稿时间：1994-12-05 |
| 摘要点击次数: 1291 |
| 全文下载次数: 1202 |
| 张卫华,忻新泉.[Fe(Phen)3](ClO4)3与Na2SO3在室温下的固相氧化还原反应[J].无机化学学报,1995,11(4):367-370. |
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