| 单取代色氨酸四苯基卟啉及其配合物的合成、结构表征及催化性质研究 |
| SYNTHESIS,CHARACTERIZATION AND CATALYTIC PROPERTIES OF MONOSUBSTITUTED TRYPTOPHANE TETRAPHENYLPORPHYRIN AND ITS COMPLEXES |
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| 摘要: |
| 关键词: 色氨酸金属卟啉 合成 配合物 催化 |
| 基金项目: |
| Abstract: A meso-5-[(p-N-tryptophane butoxyl)phenyl-10,15,20-tri(p-chlorophenyl) por-phyrin(H2L) and its complexes ML(Cl)[M=Fe(1),Co(2) and Mn(3)] were synthesized and characterized by elemental analysis,IR,UVcis,Raman and fluorescence spectra.The oxidation of aromatic aldehydes with O2 has been investigated in the presence of complexes. The oxygen uptake volume of ML (Cl) during the course of the reaction was measured. It was observed the complexes 1-3 can all catalyze the oxidation aromatic aldehydes,while H2L is inactive.The O2 maximum uptaking rates are 3.4,3.3 and 3.4 (ml/ min) respectively.In addition it was studied that the effect of tryptophane metalloporphyrin concentration,temperature,solventand substrate on oxidation of aromatic aldehydes. |
| Keywords: tryptophane metalloporphyrin synthesis complex catalytic |
| 投稿时间：1995-02-27 |
| 摘要点击次数: 1443 |
| 全文下载次数: 1903 |
| 王静秋,倪春林.单取代色氨酸四苯基卟啉及其配合物的合成、结构表征及催化性质研究[J].无机化学学报,1996,12(1):85-87. |
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