| 萃取剂HDEHP在不同稀释剂中的聚合性质 | |
| DIMERIC PROPERTY OF HDEHP IN DIFFERENT DIL UENTS | |
| 摘要: | |
| 关键词: 二(2-乙基己基)磷酸 二聚常数 稀释剂 | |
| 基金项目: | |
| Abstract: The dimeric property of bis(2-ethylhexyl) phosphoric acid(HDEHP) in different diluents has been studied. The experimental results show that the dimeric degree of HDEHP increases with the decrease of the polarity of diluents.This kind of effect has been discussed from the point of view of intermolecular interactions between the extractant molecules and the diluent ones. The dimeric constantswere related to the physical constants and experiencial parameters of the diluents.The following expression hasbeen obtained lgK2 =6.459-4.464(ε-1)/(2ε+ 1)-1.965(nD2-1)/(nD2 +1)-3.199α-5.66β. | |
| Keywords: bis(2-ethylhexyl) phosphoric acid dimeric constant diluent | |
| 投稿时间：1995-06-12 | |
| 摘要点击次数: 975 | |
| 全文下载次数: 1708 | |
| 孙国新,杨永会,鲍猛,崔玉,孙思修.萃取剂HDEHP在不同稀释剂中的聚合性质[J].无机化学学报,1996,12(2):212-214. | |
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