| 三苯基氧化膦与氯金酸配合物的热分解反应动力学 |
| STUDIESON KINETICSOF THERMAL DECOMPOSITION OF COMPLEX-HAu Cl4·H2O·4(C6H5)3 PO |
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| 摘要: 本文报道了三苯基氧化膦与氯金酸形成的配合物HAuCl4·H2O·4(C6H5)3PO的非等温热分解动力学,采用微分与积分相结合的方法,推断出了它的热分解反应机理,其热分解动力学方程为:dα/dt=A/Φe-E/RT(3/2)(1+α)(2/3)[(1+α)(1/3)-1]-1. |
| 关键词: 金 三苯基氧化膦 热分解反应动力学 |
| 基金项目: 国家自然科学基金资助项目 |
| Abstract: In this paper,the thermoanalysis of title complex was studied. Kinetic parameters were obtained from analysisof TG,DTG curvesby integral and differential methods.The possible reaction mechanism was suggested by comparison of the kinetic parameters.The kinetic equation may be expressed as: dα/dt=A/Φe-E /RT(3/2) (1+α)(2/3)[(1+α)(1/3)-1]-1. |
| Keywords: gold triphenyl phosphinoxide kinetics of thermal decomposition |
| 投稿时间：1995-07-17 |
| 摘要点击次数: 1170 |
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| 杨永会,孙国新,赵玉亭,杨延钊,孙思修.三苯基氧化膦与氯金酸配合物的热分解反应动力学[J].无机化学学报,1996,12(2):215-217. |
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