硅藻土表面酸性质的研究
A STUDY ON SURFACE ACID SITE PROPERTIES OF LOCAL DIATOM ITES
作者单位
杨宇翔 同济大学化学系, 上海200092 
吴介达 同济大学化学系, 上海200092 
王鹏 同济大学化学系, 上海200092 
陈荣三 南京大学配位化学研究所, 配位化学国家重点实验室, 南京210093 
戴安邦 南京大学配位化学研究所, 配位化学国家重点实验室, 南京210093 
摘要: 研究了几种硅藻土的表面羟基结构、表面酸性质及其孔结构,发现除浙江白土表面具有双生的硅羟基外,其他只有连生与孤立的硅羟基;硅藻土中均存在少量的B酸和L酸;硅藻土酸性质及经NH4Cl或HCl活化后的酸性质变化与硅藻土孔结构、表面结构有关。焙烧温度升高,硅藻土酸强度增加,酸量减少。
关键词: 硅藻土  酸性质  结构
基金项目: 国家自然科学基金
Abstract: In thispaper, surface structure, pore structure and surface acid sitepropertiesof several kinds diatomitewere studied Itwas found that therewas joined hydroxyl groups in Zhejiang white soil, only isolated and adjacent hydroxyl groups were found in other diatomite. Also there was some Lacid and B acid in diatom ite The acid site p roperties of diatom ites untreat-ed aswell as treated with NH4Cl or hydrochloric acidwere all concernedw ith pore structure,surface structure of diatom ite. As roast temperature increased, the acid site strength of diatomite increased, and the acid site amount gradually decreased.
Keywords: diatomite  acid site property  structure
投稿时间:1995-09-22 
摘要点击次数:  1112
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杨宇翔,吴介达,王鹏,陈荣三,戴安邦.硅藻土表面酸性质的研究[J].无机化学学报,1996,12(4):356-361.
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