| Mo(W)-Cu(Ag)-S簇合物的拓扑学研究 |
| TOPOLOGICAL RESEARCH OF THE Mo(W)-Cu(Ag)-S Cluster |
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| 摘要: 本文给出了一种由Mo(W)-Cu(Ag)-S簇合物分子式导出可能结构的拓扑方法。作为例子，文中利用该方法导出了四核单Mo(W)簇合物的各种可能结构，并预测了簇合物［Mo2O2S6Cu4(PPh3)4］的各种可能结构。本文介绍的拓扑方法，为Mo(W)-Cu(Ag)-S簇合物的结构提供了一个组织框架，也为预测簇合物的新结构提供了一个合理的基础和途径。 |
| 关键词: 簇合物结构 连接矩阵 拓扑方法 |
| 基金项目: |
| Abstract: A topological method is outlined for deducing the possible structures from the given molecular formula of Mo(W)-Cu(Ag)-S clusters. As examples, the method is applied to deduce all possible structures of tetranuclear mono-Mo(W) clusters and predict the structure of the cluster ［Mo2O2S6(PPh3)4)］. The topological method introduced here provides an organizational framework for structures of Mo(W)-Cu(Ag)-S clusters, and offers an appropriate basis for predicting accessible new structures. |
| Keywords: structure of cluster connectivity matrix topological method |
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| 摘要点击次数: 1488 |
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| 金琼花,刘建明,忻新泉,陶荣达.Mo(W)-Cu(Ag)-S簇合物的拓扑学研究[J].无机化学学报,1997,13(1):95-100. |
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