| 以氨基酸酯为轴向配体的铁、锰卟啉配合物的合成及表征 |
| SYNTHESIS AND CHARACTERIZATION OF IRON AND MANGANESE PORPHYRIN COMPLEXES WITH AMINO-ACID-ESTERS AS AXIAL LIGAND |
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| 摘要: |
| 关键词: 铁卟啉 锰卟啉 氨基酸酯 合成 表征 |
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| Abstract: The new six-coordinate complexes (TPP)FeⅡ(Gly-OMe)2 C50H42FeN6O4 and (TPP)FeⅡ(β-Ala-OMe)2 (C52H46FeN6O4) wbere TPP=meso-tetraphenyl porphyrinate, Gly-OMe=glycine methyl ester, β-Ala-OMe=β-alanine methyl ester and five-coordinte complex (TPP)Mn(Ⅱ)(Gly-OMe) (C47H35MnN5O2) have been prepared by sodium borohydride method.These complexes were characterized by UV-Vis, IR, ESR, spectra and by elemental analysis. The synthesized divalent iron porphyrins are d6 low spin states and their UV-Vis spectra are Hypso type; while divalent manganese porphyrin is d5 high spin state and its UV-Vis spectrum is pseudo-Normal type. |
| Keywords: iron porphyrin manganese porphyrin amino acid ester systhesis characterization |
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| 穆林静,邱晓航,周永洽,黄杰生,申泮文.以氨基酸酯为轴向配体的铁、锰卟啉配合物的合成及表征[J].无机化学学报,1997,13(3):344-346. |
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