| 新型大分子席夫碱配合物的合成和表征 |
| SYNTHESIS AND CHARACTERIZATION OF NOVEL SCHIFF-BASE COORDINATION POLYMERS |
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| 摘要: 本文用胺基封端聚四氢呋喃(Mn=862)与水杨醛反应，生成新型席夫碱遥爪配体，再与金属离子(Fe3+, Co2+, Cu2+)反应，得到新型大分子席夫碱配合物。用IR、ESR、UV、循环伏安法、拉伸和动态粘弹谱等表征手段对配合物进行了研究。证明所得配合物的配位结构与血红蛋白分子的功能片段的配位结构相似，钴配合物具有与血红蛋白分子相近的可逆化学吸附功能。 |
| 关键词: 大分子配合物 席夫碱 血红蛋白 |
| 基金项目: |
| Abstract: Polamine (Mn=862), which is 4,4′-Diamino Polytetrametylene Oxide Bengoate, reacted with O-Hydroxy Benzaldehyde to form novel ligand of schiff-base, and then complexed with ion (Fe3+, Co2+, Cu2+) to form new coordination polymers which have structure similar with the function segment of Hb(hemoglobin) and were characterized by IR, UV, ESR, dynamic mechanical testing, stain-stress and cyclic voltammogram. The sample which coordinated with Co2+ have similar function to Hb. |
| Keywords: coordination polymers Schiff-base Hb(hemoglobin) |
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| 林沁,谌东中,余学海.新型大分子席夫碱配合物的合成和表征[J].无机化学学报,1998,14(3):287-291. |
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