胆固醇对卵磷脂有序体中生成CaCO3晶型的影响
EFFECTS OF CHOLESTEROL ON THE STRUCTURE OF CaCO3 IN LECITHIN ORGANIZED ASSEMBLY
作者单位
吴冰 武汉大学分析测试科学系武汉 430072 
姚松年 武汉大学分析测试科学系武汉 430072 
童华 武汉大学分析测试科学系武汉 430072 
钟桂荣 武汉大学分析测试科学系武汉 430072 
摘要: 报道了在卵磷脂、胆固醇、橄榄油、电解质溶液组成的分子有序组合体中,胆固醇的加入影响了有序体的膜结构、表面特性,从而也影响到有序体微环境中所生成的CaCO3晶体结构。随着胆固醇含量增加,在一定范围内球霰石的相对含量增大;油包水体系中生成的球霰石相对含量远大于水包油体系中生成的球霰石相对含量。
关键词: 卵磷脂 胆固醇 方解石 球霰石
基金项目: 
Abstract: The effects of cholesterol on the structure of CaCO3 grown in the organized molecular assembly composed by Lecithin, cholesterol, olive oil and electrolyte has been studied as a biomembrane mimetic system. Result shows that cholesterol has a powerful influence on the membrane′s structure and the Zeta potential in vesicle, and the structure of CaCO3. With the increase of mole concentration of cholesterol, the relative concentration of vaterite CaCO3 is increased. The amount of vaterite CaCO3 is formed in the system of W/O more than in the system of O/W.
Keywords: lecithin cholesterol calcite vaterite
 
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吴冰,姚松年,童华,钟桂荣.胆固醇对卵磷脂有序体中生成CaCO3晶型的影响[J].无机化学学报,1999,15(3):341-346.
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