配位聚合物
Coordination Polymers
作者单位
张琳萍 郑州大学化学化工学院, 郑州450052 
侯红卫 郑州大学化学化工学院, 郑州450052 
樊耀亭 郑州大学化学化工学院, 郑州450052 
程凤宏 郑州大学化学化工学院, 郑州450052 
摘要: 配位聚合物是通过过渡金属和有机配体的自组装而形成的,它结合了复合高分子和配位化合物两者的特点,表现出其独特的性质,在非线性光学材料、磁性材料、超导材料及催化等诸多方面都有极好的应用前景。本文根据有机配体种类的不同,将配位聚合物分为五大类,以便于对它们进行研究。
关键词: 配位化合物  聚合物  自组装
基金项目: 国家自然科学基金资助项目(No.29941001)
Abstract: Coordination polymers are a kind of novel supramolecular compounds, formed by the self assembly of transition metals and organic ligands. They represent a new and active area of coordination chemistry because of their special roles in magnetic materials, non linear optical materials, catalysis, etc. In order to undertake further research, we classify the existing coordination polymers into five categories: 1. heterocyclic coordination polymers; 2. CNcontaining coordination polymers; 3. oxygen ligand containing coordination polymers; 4. coordination polymers containing two kinds of organic ligands; 5. coordination polymers with two kinds of metals.
Keywords: coordination compounds  polymers  self-assembly
投稿时间:1999-07-05 修订日期:1999-08-10
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张琳萍,侯红卫,樊耀亭,程凤宏.配位聚合物[J].无机化学学报,2000,16(1):1-12.
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