水合盐的几种脱水过程探讨
A Study on the Dehydration of Some Hydrated Salts
作者单位
冯海燕 河北师范大学化学系, 石家庄050016 
刘晓地 河北师范大学化学系, 石家庄050016 
葛艳蕊 河北科技大学化工系, 石家庄050011 
武克忠 河北师范大学化学系, 石家庄050016 
张建军 河北师范大学试验中心, 石家庄050016 
摘要: 通过差热/热重联机(DTA/TGA)和差示扫描量热法(DSC)测定几种盐(Na2SO4·10H2O、CuSO4·5H2O、Na2S2O3·5H2O)的失水过程,对水合盐脱水过程几种可能的类型进行探讨。研究表明低温(100℃以下)水合盐脱水有两种类型,一种直接失去气态水,另一类先脱去液态水再进一步变为气态水。并从
关键词: 水合盐  脱水过程  热分析  热力学
基金项目: 河北省教委专项科研项目(No.97116)
Abstract: Various possible types of dehydration of hydrated salt (Na2SO4·10H2O,CuSO4·5H2O,Na2S2O3·5H2O) have been studied by means of on line Differential Thermal Analysis and Thermogravimetry(DTA/TG) and Differential Scanning Calorimetry(DSC).The experimental results showed that there is two different type of dehydration for studied salt. In one case, the hydrated salt loses water vapordirectly, and in the other case,which loses liquid water first and then the losing water is transformed into vapor. For those cases were discussed in terms of thermodynamics.
Keywords: hydrated salt  dehydration  thermal analysis  thermodynamics
投稿时间:1999-06-08 修订日期:1999-08-24
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冯海燕,刘晓地,葛艳蕊,武克忠,张建军.水合盐的几种脱水过程探讨[J].无机化学学报,2000,16(1):89-96.
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