氯·氨荒酸基·二丁基锡(Ⅳ)配合物的合成和性质 |
Synthesis and Properties of Chlorodibutyltin(Ⅳ) Complexes of Carbamodithioate |
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摘要: 合成了13种新的氯·氨荒酸基·二丁基锡(Ⅳ)配合物(nC4H9)2Sn(C1)S2CNRR′。通过元素分析、IR、UV、1H NMR及MS对这些配合物进行了表征,结果表明,氨荒酸基是以双齿形式与锡原子配位。初步生物活性测试表明,部分配合物具有较强的抗癌活性。 |
关键词: 二丁基锡 氨荒酸 合成 生物活性 |
基金项目: 山东省自然科学基金(No.Q98B01117) |
Abstract: Thirteen new chlorodibutyltin(Ⅳ) complexes of caxbamodithioate [(n-C4H9)2Sn(Cl)S2CNRR′] IR, UV, 1H NMR and MS. These results revealed that the carbamoditioate ligand were coordinated to Sn in a bidentate fashion. Preliminary study of their biological activity showed that some of them had better antitumour activity. |
Keywords: dibutyltin carbamodithioic acid synthesis biological activity |
投稿时间:1999-12-10 修订日期:2000-04-20 |
摘要点击次数: 1375 |
全文下载次数: 1885 |
尹汉东,王传华,张如芬,马春林.氯·氨荒酸基·二丁基锡(Ⅳ)配合物的合成和性质[J].无机化学学报,2000,16(4):619-623. |
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