高温气相合成纳米TiO2-Al2O3复合颗粒的形态
Morphology of High Temperature Vapor-Phase Synthesized Nanophase TiO2-Al2O3 Composite Particles
作者单位
施利毅 上海大学理学院化学系, 上海200072
华东理工大学技术化学物理研究所上海 200237 
李春忠 华东理工大学技术化学物理研究所上海 200237 
房鼎业 华东理工大学化工系, 上海 200237 
古宏晨 华东理工大学技术化学物理研究所上海 200237 
朱以华 华东理工大学技术化学物理研究所上海 200237 
陈爱平 华东理工大学技术化学物理研究所上海 200237 
摘要: 
关键词: 纳米颗粒  气相反应  功能陶瓷
基金项目: 国家计委九五攻关项目(No.9655402);国家自然科学基金(No.29506045)
Abstract: Nanophase TiO2-Al2O3 composite particles synthesized by gas phase oxidation of TiCl4 and AlCl3 in an aerosol reactor were characterized by EDS, XPS, TG-DTA, TEM, XRD and BET surface area analysis. The results showed that the morphological structure of the composite particles were influenced by AlCl3 feed ratio and reaction temperature. When Xinlet=2.80 and T=1400℃, the composite particles were mainly composed of rutile TiO2,α Al2O3, and Al2TiO5, the average particle size was 25.3 nm and GSD (Geometric tandaed Squace Deviation) was 1.51. Other processing parameters affecting the particle size was also analyzed.
Keywords: nanophase particles  vapor-phase reaction  functional ceramic
投稿时间:1999-10-18 修订日期:2000-01-24
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施利毅,李春忠,房鼎业,古宏晨,朱以华,陈爱平.高温气相合成纳米TiO2-Al2O3复合颗粒的形态[J].无机化学学报,2000,16(4):683-687.
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