| 一维链状有机锡配位聚合物[(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n的合成及晶体结构 |
| Synthesis and Crystal Structure of t he One-dimensional Infinite Chain Organotin Coordination Polymer,[(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n |
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| 摘要: |
| 关键词: 一维无限链 有机锡配合物 4-吡啶甲酸 合成 晶体结构 |
| 基金项目: 教育部骨干基金;山东省自然科学基金资助项目(No.Y2000B08) |
| Abstract: [(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n was synthesized by the reaction of 4-pyridine car-boxylic acid with the tribenzyltin oxide and was characterized by IR,1H NMR and MS.Its crystal structure was determined by X-ray single crystal diffraction.The crystal belongs to monoclinic.The space group P21/c with unit cell parameters a=1.2241(8)nm,b=0.9660(6)nm,c=2.3708(15)nm,β=102.722(12)°,V=2.734(3)nm3,Z =4,Dc=1.298g·cm-3.In crystal,the tin atom rendered five-coordinate in a trigo nal bipyramidal structure which is bridged by 4-pyridine carboxy-late into one-dimensional chain polymers. |
| Keywords: one-dimensional infinite organotin complex 4-pyridine carboxylic acid synthesis crystal structure |
| 投稿时间：2001-05-28 修订日期：2011-07-20 |
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| 尹汉东,王传华,王勇,马春林.一维链状有机锡配位聚合物[(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n的合成及晶体结构[J].无机化学学报,2001,17(6):896-900. |
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