| Fe/La2O3纳米催化剂制备碳纳米管 |
| Carbon Nanotubes Syntheses on a Fe/La2O3 Nanocatalyst |
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| 摘要: |
| 关键词: 碳纳米管 乙炔 铁酸镧 铁催化剂 纳米 |
| 基金项目: |
| Abstract: Nanocrystalline LaFeO3 was synthesised by the citrate method with La(NO3)3·6H2O,Fe(NO3)3·9H2O and citric acid as the raw materials. Before and after reduction, its structure was characterized by means of X-ray diffraction and transmission electron microscopy(TEM). And after reduction of LaFeO3 oxide, the rare earth oxide, La2O3, prevents Fe particles from agglomerating and promotes the dispersion of nano-scale Fe particles (ca.40nm), which is one of the key factors for the growth of carbon nanotube. The carbon nanotubes from the catalytic de-composition of C2H2 were obtained using Fe/La2O3 nano-scale catalyst, which was formed from LaFeO3 oxide as the catalyst precursor. The morphological structures of the carbon nanotube obtained have been examined by TEM. The results indicate that they are multi-walled nanotubes of good quality with inter diameter ranging from 20～25nm and length ranging from 25～40μm. The yields of carbon nanotube are 1.25g·gcat-1 at the reaction temperature of 973K for 30min. |
| Keywords: carbon nanotube acetylene LaFeO3 iron catalyst nanometer |
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| 彭峰,江剑城,雷建光.Fe/La2O3纳米催化剂制备碳纳米管[J].无机化学学报,2002,18(2):190-192. |
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