| 邻苯二胺合钴氧合反应的研究Ⅰ 水溶液中配合物及其氧合配合物稳定常数的测定 |
| The Study on Oxygenation of o-Phenylenediamine Cobalt Complexes Determination of the Stability Constants of Complexes and Oxygenated Complexes in Aqueous Solution |
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| 摘要: |
| 关键词: 氧载体 邻苯二胺 钴 氧合作用 配位常数 |
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| Abstract: In this paper, the stability constants of the o-Phdn-Co complexes and oxygenated complexes were determined by pH potentiometry for the first time. The determined method was verified with the known o-Phdn-Cu system by comprising the stability constants obtained from experiment results with those in literatures. The calculated results of oxygenated complexes were confirmed by spectrophotometry. All the results are agreed very well, which show the correctness of the determination. |
| Keywords: oxygen-carrier o-phenylenediamine cobalt oxygenation coordination-constants |
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| 岳凡,王吉德,张翼,宋启军,李兴寿.邻苯二胺合钴氧合反应的研究Ⅰ 水溶液中配合物及其氧合配合物稳定常数的测定[J].无机化学学报,2002,18(5):489-492. |
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