CuO超细粉体的形貌与红外特性研究
Study on the Morphology and Infrared Spectrum Behavior of Ultrafine Powder CuO
作者单位
王文亮 陕西师范大学化学与材料科学学院,西安 710062 
李东升 延安大学化学化工系,化学反应工程省级重点实验室,延安 716000 
王振军 西北大学化学系,西安 710069 
崔华莉 延安大学化学化工系,化学反应工程省级重点实验室,延安 716000 
薛岗林 西北大学化学系,西安 710069 
摘要: 
关键词: CuO 超细粉体 形貌特征 红外特性 催化活性
基金项目: 
Abstract: Ultrafine Powder CuO was prepared by direct-heating Cu2(OH)2CO3 in different calcination temperatures. XRD, FT-IR, SEM and surface area measurement techniques were used to investigate the properties of the CuO powder. The results show that the decomposition temperature has remarkably effect on crystallite size, morphology, surface structure, IR behavior and activity of the powder for H2O2 decomposition. The major morphology of the particle is fluffy-sphered in the lower temperature, which is consists of small sheets of crystallite. With the in-creasing of calcination temperature, crystal of CuO grows up, the fluffy-sphered particle reduces and catalytic ac-tivity decreases. FT-IR patterns revealed that the absorption of Cu-O and -OH bond in CuO ultrafine powder were red-shifted.
Keywords: CuO ultrafine powder morphology character infrared behavior catalytic activity
 
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王文亮,李东升,王振军,崔华莉,薛岗林.CuO超细粉体的形貌与红外特性研究[J].无机化学学报,2002,18(8):823-826.
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