| 一维链状配位聚合物[M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ)，Cu(Ⅱ)]的合成及晶体结构表征 |
| Synthesis and Crystal Structure of One-Dimensional Coordination Polymers [M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ)，Cu(Ⅱ)] |
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| 摘要: 设计并合成了一个含吡啶基团的柔性配体：N，N′-Bis(3-pyridylmethyl)-1，4-benzenedimethylamine(bpb)。通过bpb与硫酸锌及硫酸铜反应得到了两个新型具有一维链状结构的配位聚合物：[M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ) 1，Cu(Ⅱ) 2]。X-射线晶体结构测定表明，这两个 |
| 关键词: 铜(Ⅱ)配合物 锌(Ⅱ)配合物 配位聚合物 晶体结构 |
| 基金项目: |
| Abstract: A new flexible ligand， N，N′-bis(3-pyridylmethyl)-1，4-benzenedimethylamine (bpb) was designed and syn-thesized. Two coordination polymers， [M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ)1，Cu(Ⅱ) 2]， were obtained by the reactions of ZnSO4·7H2O and CuSO4·5H2O with bpb. The two compounds were characterized by X-ray crystallography. They crystallize in triclinic with same space group P1. The crystallographic data of compound 1 are： a=11.8055(12)?， b=11.8778(12)?， c=12.1840(13)?， α=80.763(2)°， β=71.982(2)°， γ=80.913(2)° and those of complex 2 are： a=11.7403(19)?， b=11.890(2)?， c=12.254(2)?， α=71.339(3)°， β=81.936(4)°， γ=80.917(4)°. CCDC： 192998(1)， 192999(2). |
| Keywords: copper(Ⅱ) complex zinc(Ⅱ) complex coordination polymers crystal structure |
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| 朱惠芳,李玲,樊健,赵伟,孙为银.一维链状配位聚合物[M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ)，Cu(Ⅱ)]的合成及晶体结构表征[J].无机化学学报,2003,19(1):25-28. |
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