水热合成新型硼磷酸盐化合物的研究进展
Research Development of New Borophosphates Prepared by Hydrothermal Method
作者单位E-mail
柳伟 高性能陶瓷和超微结构国家重点实验室, 中国科学院上海硅酸盐研究所, 上海, 200050  
赵景泰 高性能陶瓷和超微结构国家重点实验室, 中国科学院上海硅酸盐研究所, 上海, 200050 jtzhao@sic.ac.cn 
摘要: 作为潜在的新型功能材料,硼磷酸盐近几年得到了科学家的极大重视.本文从结构化学角度对水热合成硼磷酸盐化合物进行了总结,并着重对过渡金属、P区主族元素和含有机模板硼磷酸盐化合物所具有的典型结构进行了描述和归类,同时还讨论了硼磷酸盐的最新研究进展及其发展方向.
关键词: 硼磷酸盐  水热合成  晶体结构
基金项目: 国家自然科学基金委杰出青年基金(无机化学No.20025101);上海市光科技发展基金(No.022261015);国家科技部863计划课题(No.2002AA324070)资助项目
Abstract: Borophosphates as a new type of potential functional materials have attracted much attention of scientists in the last few years. Other than conventional solid state reaction method, hydrothermal method have been proved to be efficient in synthesizing such kind of compounds with variety of structures. The typical structure features in consideration of different partial anionic structures of transition metal and main group metal borophosphates synthesized by hydrothermal methods have been reviewed in detail in this paper. The new prospects of borophosphate researches, such as synthesis with organic molecule templates or with early transition metals and potential applications have also been discussed.
Keywords: borophosphate  hydrothermal method  crystal structure
投稿时间:2003-04-10 修订日期:2003-05-26
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柳伟,赵景泰.水热合成新型硼磷酸盐化合物的研究进展[J].无机化学学报,2003,19(8):793-801.
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