过饱和度、反应物化学计量比及离子强度对草酸钙晶体生长的影响
Effect of Supersaturation, Stoichiometrical Ratio and Ionic Strength on Crystallization of Calcium Oxalate
作者单位
郑辉 暨南大学生物矿化与结石病防治研究所化学系广州 510632 
李祥平 暨南大学生物矿化与结石病防治研究所化学系广州 510632 
欧阳健明 暨南大学生物矿化与结石病防治研究所化学系广州 510632 
摘要: 
关键词: 草酸钙  过饱和度  离子强度  化学计量比  凝胶  尿结石
基金项目: 
Abstract: The effect of supersaturation, oxalate/calcium stoichiometrical ratio (Oxa2-/Ca2+) and ionic strength on the crystallization of calcium oxalate (CaOxa) was investigated in gel systems by a double diffusion technique. The supersaturation affects the morphology, phase composition, and aggregation of CaOxa crystals. To a certain concentration, the effect of Oxa2- ions on the aggregation of calcium oxalate monohydrate (COM) was much stronger than that of Ca2+ ions. It indicated that the increase of the concentration of Oxa2- ions can more efficiently promote the formation of CaOxa stones. The increase of ionic strength and the molar ratio of Ca2+/ Oxa2- also promotes the aggregation of COM crystals.
Keywords: calcium oxalate  supersaturation  ionic strength  stoichiometrical ratio  gel  urinary stone
投稿时间:2005-02-22 修订日期:2005-05-09
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郑辉,李祥平,欧阳健明.过饱和度、反应物化学计量比及离子强度对草酸钙晶体生长的影响[J].无机化学学报,2005,21(9):1375-1378.
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