| 消旋的有机二磺酸三邻菲咯啉锌配合物(英) |
| (Δ,Λ)-[Tris（1,10-phenanthroline）Zn(Ⅱ)][(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disulfonate] |
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| 摘要: |
| 关键词: 无机手性； 6,6′-二溴-2,2′-二甲氧基-1,1′-二萘-4,4′-二磺酸 锌 |
| 基金项目: |
| Abstract: Compound [Zn(phen)3][BDA] (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disulfonate, phen= 1,10-phenanthroline) composes of the anion part (racemic-(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disulfonate ) and the cation part which consists of a racemic octahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC: 277924. |
| Keywords: inorganic chirality 6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene -4,4′-disulfonic Zinc(Ⅱ) |
| 投稿时间：2005-02-15 修订日期：2005-06-01 |
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| 黄雪峰,钱坤.消旋的有机二磺酸三邻菲咯啉锌配合物(英)[J].无机化学学报,2005,21(9):1437-1438. |
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