| Abstract: Reactions of bitter salt with taurine-3,5-dibromo-salicylaldehyde schiff base gave one new Complex
[Mg(Br2TSSB)(Phen)(H2O)]·H2O (Br2TSSB=Taurine 3,5-dibromo-Salicylaldehyde Schiff Base, phen=o-phenanthroline), which was characterized by elemental analysis, IR and X-ray diffraction. The chemical formula weight of the complex is 625.58. It′s crystal belongs to monoclinic system with space group
P21/c. The cell parameters are: a=1.814 2(3) nm, b=0.814 75(14) nm, c=1.641 7(3) nm, β=90.571(4)°, and Z=4, V=2.426 4(7)
nm3, Dc=1.712 g·cm-3, F(000)=1 248, μ=3.496 mm-1. The complexes form a 3D net structure in which they are connected with hydrogen bonds and π-π stacking. The Mg(II) formed a distorted coordination tetragonal pyramid. CCDC: 286194. |
| 辛懋,张淑华,杜荣斌,蒋毅民,孙伟娜,廖松明.牛磺酸缩3，5-二溴水杨醛席夫碱镁配合物[Mg(Br2TSSB)(Phen)(H2O)]·H2O的合成及晶体结构[J].无机化学学报,2006,22(1):179-182. |
