一步法合成双亲的Ag,Cu,Cd和Ni纳米金属单质
Single-step Synthesis of Amphiphilic Nanostructured Ag, Cu, Cd and Ni
作者单位
李新昊 吉林大学化学学院无机合成与制备化学国家重点实验室长春 130012 
曹学静 吉林大学化学学院无机合成与制备化学国家重点实验室长春 130012 
张东慧 吉林大学化学学院无机合成与制备化学国家重点实验室长春 130012 
陈接胜 吉林大学化学学院无机合成与制备化学国家重点实验室长春 130012 
摘要: 本文报道利用简单的溶剂热方法,以相应的金属盐作为唯一的反应物来制备Ag,Cu,Cd,Ni等纳米结构金属。采用XRD,SEM,TEM等测试手段对产物进行了表征。实验结果表明,反应条件特别是反应时间对产物最后的化学组成起重要作用。该制备方法具有一定的普适性,而且简单实用;涉及的反应条件相对温和,获得的产物具有双亲性质,能均匀分散于大部分极性和非极性溶剂中。
关键词: 溶剂热法  过渡金属  纳米结构  双亲
基金项目: 
Abstract: Nanostructured Ag, Cu, Cd, Ni were synthesized using the corresponding metal salts as mono-precursors via a facile solvothermal method, and the products were characterized by XRD,SEM and TEM. It is proved that the reaction time plays a key role in determining the composition of the products. This simple and general process is environment-friendly, and the products obtained are amphiphilic and dispersible well in most of the polar and nonpolar solvents.
Keywords: Nanostructured Ag, Cu, Cd, Ni were synthesized using the corresponding metal salts as mono-precursors via a facile solvothermal method, and the products were characterized by XRD,SEM and TEM. It is proved that the reaction time plays a key role in determi
 
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李新昊,曹学静,张东慧,陈接胜.一步法合成双亲的Ag,Cu,Cd和Ni纳米金属单质[J].无机化学学报,2006,22(8):1401-1405.
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