| 吖啶-咪唑配体镉(Ⅱ)配合物的合成、表征及阴离子效应 |
| Synthesis, Crystal Structure and Anion Effect of Cd(Ⅱ) Complexes with Acridine-imidazole Ditopic Ligand |
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| 摘要: 本文报道一个吖啶-咪唑双功能配体L[9-(1-咪唑基)吖啶]的2个镉(Ⅱ)配合物[Cd(L)2(NO3)2] (1)和[Cd(L)2(Ac)(NO3)(H2O)](H2O)3 (2)的合成及结构表征，并探讨了阴离子对配合物结构的影响，结果表明：不同的阴离子对配合物的结构具有重要影响。 |
| 关键词: 吖啶-咪唑配体 晶体结构 π-π堆积 阴离子效应 |
| 基金项目: |
| Abstract: Two new Cd(Ⅱ) complexes with acridine-imidazole ditopic ligand L (L=9-(1-imidazolyl)acridine), [Cd(L)2(NO3)2] (1) and [Cd(L)2(Ac)(NO3)(H2O)](H2O)3 (2), were synthesized and structurally characterized by IR and single crystal X-ray structural analysis. 1 has a 1D chain structure bridged by NO3- anions, whereas 2 takes a mononuclear structure. The structural difference of the two complexes is attributable to the difference of counter anions. CCDC: 606068, 1; 606069, 2. |
| Keywords: acridine-imidazole ligand crystal structure π-π stacking anion influence |
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| 王军杰,刘春森,常泽,闫莉芬,卜显和.吖啶-咪唑配体镉(Ⅱ)配合物的合成、表征及阴离子效应[J].无机化学学报,2006,22(8):1443-1448. |
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