| 四（1-乙烯基咪唑）二异硫氰酸镉的晶体结构和电化学性能(英文) | |
| Crystal and Electrochemical Property of Tetrakis(1-vinyl-1H-imidazole-kN3)diisothiocyanatocadmium(II) | |
| 摘要: | |
| 关键词: 镉(II)配合物 硫氰根配合物 循环伏安 晶体结构 | |
| 基金项目: | |
| Abstract: A complex [Cd(NCS)2(Vim)4] (where Vim=1-vinylimidazole) was synthesized and it′s crystal structure was determined by X-ray diffraction technique. The compound crystallizes in the Monoclinic space group P21/c with the parameters: a=0.858 50(17) nm, b=0.909 90(18) nm, c=1.782 3(4) nm, β=100.14(3)°, V=1.370 5(5) nm3, Z=2. In the structure, each Cd atom is coordinated by four 1-vinylimidazole ligands and a pair of monodentate isothiocyanic groups, affording a compressed octahedral CdN6 core. The NCS- anions are trans and four N atoms from the 1-vinylimidazole ligands define the equatorial plane. From the cyclic voltammogram measurement in H2O, we know that the electrode reaction was a quasi-reversible process. CCDC: 630897. | |
| Keywords: cadmium(II) complex thiocyanato complex cyclic voltammetry crystal structure | |
| 摘要点击次数: 1330 | |
| 全文下载次数: 1268 | |
| 刘光烨,陈红纳,刘法谦,李少香,李荣勋,黄素逸.四（1-乙烯基咪唑）二异硫氰酸镉的晶体结构和电化学性能(英文)[J].无机化学学报,2007,23(6):1085-1088. | |
| 查看全文 查看/发表评论 下载PDF阅读器 | |
| Support information: | |
|
| |
|
| |
|
| |