| 基于3-乙基-2-乙酰吡嗪缩肼基甲酸甲酯的铜和锌配合物的晶体结构及荧光性质 | |
| Cu(Ⅱ) and Zn(Ⅱ) Complexes Based on Methyl (1-(3-Ethylpyrazin-2-yl)ethylidene)carbazate:Crystal Structures and Fluorescence Properties | |
| 摘要: 合成并通过单晶X射线衍射、元素分析及红外光谱表征了配合物[Cu（HL）Cl2]·H2O（1）和[ZnL2]（2）的结构（HL为3-乙基-2-乙酰吡嗪缩肼基甲酸甲酯）。单晶衍射结果表明，在配合物1中，Cu（Ⅱ）离子拥有四方锥配位构型，与一个中性配体HL和2个氯离子配位。配合物2中，Zn（Ⅱ）离子与来自2个阴离子配体L-的N2O电子供体配位，配位构型为扭曲的八面体。此外还研究了配合物1和2的固体荧光性质。 | |
| 关键词: 肼基甲酸甲酯 吡嗪 荧光 晶体结构 | |
| 基金项目: 国家自然科学基金（No.21001040）、河南省科技厅基础与前沿项目（No.162300410011）、河南省教育厅自然科学基金（No.12B15001，14B150029）和河南省青年骨干教师项目（No.2014GGJS-045）资助 | |
| Abstract: Two complexes, namely[Cu(HL)Cl2]·H2O (1) and[ZnL2] (2) (HL=methyl (1-(3-ethylpyrazin-2-yl)ethylidene) carbazate) have been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that in complex 1, the Cu(Ⅱ) ion with a distorted square pyramid coordination geometry is coordinated with one neutral ligand HL and two chloride anions. However, the central Zn(Ⅱ) ion in complex 2 is surrounded by two independent anionic ligands with N2O donor set, thus possesses a distorted octahedral coordination geometry. The luminescent properties of the complexes were also studied in detail. | |
| Keywords: methyl hydrazinocarboxylate pyrazine fluorescence crystal structure | |
| 投稿时间：2017-04-17 修订日期：2017-07-19 | |
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| 毛盼东,陈泽华,王媛,秦莉,吴伟娜,王元.基于3-乙基-2-乙酰吡嗪缩肼基甲酸甲酯的铜和锌配合物的晶体结构及荧光性质[J].无机化学学报,2017,33(10):1849-1854. | |
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