石墨相氮化碳/二氧化锡复合材料的制备及光催化性能
Preparation and Photocatalytic Activity of g-C3N4/SnO2 Composite
作者单位E-mail
宁湘 湖南大学材料科学与工程学院, 长沙 410082
喷射沉积技术及应用湖南省重点实验室, 长沙 410082 
 
武月桃 湖南大学材料科学与工程学院, 长沙 410082
喷射沉积技术及应用湖南省重点实验室, 长沙 410082 
 
王续峰 湖南大学材料科学与工程学院, 长沙 410082
喷射沉积技术及应用湖南省重点实验室, 长沙 410082 
 
刘艳丽 湖南大学材料科学与工程学院, 长沙 410082
喷射沉积技术及应用湖南省重点实验室, 长沙 410082 
yanliliu@hnu.edu.cn 
摘要: 采用热聚合法和水热法相结合的方法制备了g-C3N4/SnO2复合光催化剂。利用XRD、SEM、TEM、FT-IR和UV-Vis DRS等多种测试手段对所得样品的物相结构、微观形貌和吸光特性等进行了表征。结果表明,异质结构复合光催化剂的最大光吸收边位置相对纯相SnO2发生了明显的红移,并且SnO2颗粒均匀分布于g-C3N4表面,其中最优组分(50%-g-C3N4/SnO2)光催化降解染料罗丹明B(RhB)的效率达到了纯相g-C3N4的3.78倍。
关键词: 光催化  异质结构  石墨相氮化碳  二氧化锡  纳米颗粒
基金项目: 国家自然科学基金(No.61404046)资助项目。
Abstract: The g-C3N4/SnO2 composite had been fabricated by the combination of hydrothermal method and thermal polymerization process in this paper. The crystal structures and morphology of various samples were characterized using XRD, SEM, TEM, FT-IR, and UV-Vis DRS. The results showed that the optical absorption edge of g-C3N4/SnO2 composites with co-effect of heterojunction had an obvious red shift to the longer wavelength in comparison with pure SnO2 and SnO2 nanoparticles were dispersing on the g-C3N4 surface well. The photocatalytic degradation properties of g-C3N4/SnO2 composites on rhodamine B (RhB) were remarkably improved under visible light irradiation, and the degradation rate of optimal 50%-g-C3N4/SnO2 composite was 3.78 times as great as that of pure g-C3N4.
Keywords: photocatalysis  heterojunction  g-C3N4  SnO2  nanoparticles
投稿时间:2019-04-30 修订日期:2019-08-28
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宁湘,武月桃,王续峰,刘艳丽.石墨相氮化碳/二氧化锡复合材料的制备及光催化性能[J].无机化学学报,2019,35(12):2243-2252.
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