自组装[Pd6(L)4]8+型大环配合物用于荧光传感HSO3-
Self-assembly of [Pd6(L)4]8+-type macrocyclic complexes for fluorescent sensing of HSO3-
作者单位E-mail
牛晓菲 北京工业大学化学与生命科学学院, 北京 100124  
王珂 北京工业大学化学与生命科学学院, 北京 100124  
宋峰岩 北京工业大学化学与生命科学学院, 北京 100124 fengyansong@bjut.edu.cn 
于澍燕 北京工业大学化学与生命科学学院, 北京 100124 selfassembly@bjut.edu.cn 
摘要: 在本研究中,通过金属定向的分级自组装反应,以芳基吡唑-吡啶配体与双金属钯组装子在水溶液中合成了平行四边形的大环超分子金属环[Pd6(bpy)6(L1)4](PF6)8 (1a)和[Pd6(bpy)6(L2)4](PF6)8 (2a),其中 HL1=1-(1H-pyrazole-4-yl)-4-(4-pyridyl)benzene,HL2=9-(1H-pyrazole-4-yl)-10-(4-pyridyl)anthracene,bpy=2,2'-联吡啶。通过单晶X射线衍射证实了超分子钯平行四边形的结构。值得注意的是,这2个平行四边形金属环可以用作开启型荧光传感器,通过拆卸机制检测HSO3-。此外,基于配合物1a的传感器显示出对HSO3-的选择性检测,不受其他阴离子的干扰。检测限低至0.131 μmol·L-1。此外,配合物1a还通过荧光变化实现了在试纸模式下对HSO3-的半定量可视化检测。
关键词: 自组装  超分子钯平行四边形  荧光检测  超分子晶体  亚硫酸氢根探针
基金项目: 
Abstract: In this study, parallelogram-like macrocyclic supramolecular metallacycles [Pd6(bpy)6(L1)4](PF6)8 (1a) and [Pd6(bpy)6(L2)4](PF6)8 (2a), where HL1=1-(1H-pyrazole-4-yl)-4-(4-pyridyl)benzene, HL2=9-(1H-pyrazole-4-yl)-10-(4-pyridyl)anthracene,and bpy=2,2'-bipyridine, are synthesized by reacting aryl pyrazole pyridine ligands with dipalla-dium corners in aqueous solutions via metal-directed hierarchical self-assembly. The structures of the supramolecular Pd parallelograms are confirmed through single-crystal X-ray diffraction. Notably, the two parallelogram metallacycles can be used as“turn-on”fluorescence sensors to detect HSO3- through a disassembly mechanism. In addition, the 1a-based sensor shows selective detection of HSO3- without interference from other anions. The detection limit was as low as 0.131 μmol·L-1. Furthermore, complex 1a presented the semiquantitative visual detection ability for HSO3- in the test trip mode via fluorescence changes.
Keywords: self-assembly  supramolecular Pd parallelogram  fluorescence detection  supramolecular crystal  bisulfite probe
投稿时间:2024-02-02 修订日期:2024-05-28
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牛晓菲,王珂,宋峰岩,于澍燕.自组装[Pd6(L)4]8+型大环配合物用于荧光传感HSO3-[J].无机化学学报,2024,40(7):1233-1242.
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